Acoustic communication is a key enabler for underwater Internet of Things networks between autonomous underwater platforms. Underwater Internet of Things networks face a harsh communications environment and limited energy resources which makes them susceptible to interference, whether intentional (i.e., jamming) or unintentional. Resilient, power efficient waveforms and modulation schemes are needed for underwater acoustic communications in order to avoid outages and excessive power drain. We explore the impact of modulation scheme on the resiliency of underwater acoustic communications in the presence of channel impairments, interference, and jamming. In particular, we consider BFSK and OFDM schemes for underwater acoustic communications and assess the utility of Polar coding for strengthening resiliency.