Propagation delay and channel loss are two vital factors affecting reliability of Underwater Acoustic Networks (UANs). Different from land networks, UANs have long propagation delay and poor channel quality, which lead to serious data collision and high bit error rate, respectively. However, complex underwater environments impose great challenges to evaluate propagation delay and channel loss. As temperature is the most critical factor affecting them, in this paper, we propose to employ temperature to evaluate them. However, existing temperature prediction research are insufficient for accuracy or efficiency. This paper proposes a temperature prediction-assisted approach for evaluating propagation delay and channel loss, aiming to improve reliability and performance of underwater acoustic networks. We build a nonlinear autoregressive dynamic neural network-based temperature prediction model to improve prediction accuracy and reduce time complexity. Then, we evaluate propagation delay and channel loss considering different marine environments, including shallow and deep sea. Extensive simulation results show that our approach performs better than five advanced baselines.